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VOC burn off

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I know we always talk about letting the lump burn for 45 minutes before adding meat. My question is when doing a long cook, only about a fist full of charcoal is lit at that time. Wouldn't the Vocs come into play when ever new charcoal ignites throughout the cook. I have never had a problem, just curious about the science behind it.
Bluffton, SC LBGE, SBGE, Thermapen

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